The scene looks fine to me.
One interpretation of your question I could see is that you want - in total - only 0.1% refelction

As you have a glass surface at the front, you will always have the 4%-component from that.
From both my understanding Dade's answer and my own test on your scene, the exterior volume IOR has no effect for the glossy material.
You hence get a clear 4% specular reflection fromt he front glass surface, and a glossy component from the intermediate surface, which will be slightly diffuse because glossy has a minimum 0.001 roughness. Depending on the view angle and and the glass IOR there will also be a small refractive shift of the glossy component.